Brazed ceramic seal for batteries with titanium-titanium-6A1-4V cases

ABSTRACT

The invention includes a brazed ceramic ring that separates the positive and negative ends of the battery while still providing a leak-tight seal. The ceramic is aluminum oxide or zirconium oxide or zirconium oxide with 3% yttrium. The invention includes a brazing material that is greater than 50% gold. The invention includes a titanium alloy case (Ti-6Al-4V) which is titanium with 6% aluminum and 4% vanadium as its major alloying elements. The case has the desirable properties of titanium such as high strength for a relatively low weight; and the case has the requisite ability and electro-activity to be used a positive current carrying element where the battery&#39;s positive electrode exhibits more than 3.5 V vs. Li/Li + .

FIELD OF THE INVENTION

[0001] This invention relates to brazed ceramic seals for use in lithium ion batteries.

BACKGROUND OF THE INVENTION

[0002] A chemical battery case may act to prevent the positive and negative output devices from coming into contact, i.e., shorting. The battery case in its entirety also functions to contain and prevent leakage of battery materials such as an electrolyte. Moreover, the battery case itself must provide for mechanical strength to contain pressures originating from within the battery as well as to provide the mechanical strength for ordinary handling of the battery.

SUMMARY OF THE INVENTION

[0003] The invention includes a brazed ceramic ring that separates the positive and negative ends of the battery while still providing a leak-tight seal. The ceramic is aluminum oxide or zirconium oxide or zirconium oxide with 3% yttrium. The invention includes a brazing material, which is greater than 50% gold. The invention includes a titanium alloy case (Ti-6Al-4V) which is titanium with 6% aluminum and 4% vanadium as its major alloying elements. The case has the desirable properties of titanium such as high strength for a relatively low weight; and the case has the requisite ability and electro-activity to be used a positive current carrying element where the battery's positive electrode exhibits more than 3.5 V vs. Li/Li⁺.

BRIEF DESCRIPTION OF THE DRAWINGS

[0004] The above and other features and advantages of the invention will be more apparent from the following detailed description wherein:

[0005]FIG. 1 shows the titanium alloy battery case with titanium and titanium alloy end caps and the ceramic non-conducting ring;

[0006]FIG. 2 shows the ceramic ring sandwich with the ceramic ring between a ring of Ti and between a different ring of Ti-6Al-4V, and the gold-based braze.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

[0007] The following description is of the best mode presently contemplated for carrying out the invention. This description is not to be taken in a limiting sense, but is merely made for the purpose of describing the general principles of the invention. The scope of the invention should be determined with reference to the claims.

[0008] The battery (1), as shown in FIG. 1, is constructed of a titanium alloy case (2), the alloy being Ti-6Al-4V. This alloy is principally titanium with 6% aluminum and 4% vanadium, with oxygen, nitrogen, carbon, hydrogen and iron typically present as trace elements. One end cap (3), which completes the bottom of the positive casing, is also of the titanium alloy Ti-6Al-4V. The ceramic ring sandwich (20) is shown in FIGS. I and 2. First looking at FIG. 2, the ceramic ring (21) is brazed by the gold alloy braze (24) to a one ring of titanium (23) and the other ring of Ti-6Al-4V. (22). The gold alloy braze (24) is one which contains more than 50% gold by weight. A specific type of gold alloy braze (24) is 96.4% gold, 3.0% nickel and 0.6% titanium. Some trace elements may be present with a corresponding slight adjustment in the composition percentages. The braze is chosen so that it can stand up to the electrochemical conditions inside the battery with which it will come in contact. The ceramic ring (21) is of aluminum oxide, zirconium oxide or zirconium oxide with 3% yttrium.

[0009] Returning to FIG. 1, the ceramic ring sandwich (20) is placed on the open end of the titanium alloy case (2) with the titanium alloy ring (22) toward the case (2). The titanium ally ring (22) is then laser welded to the titanium alloy case (2). Subsequently a titanium end cap (4) with a feed-though hole (5) is laser welded to the titanium ring (23) of the ceramic ring sandwich (20).

[0010] In order to prevent any short-circuiting by way of the ceramic ring (21), it must be at least 10 μm in height (25). This arises from any diffusion of the gold alloy braze material (24) through the ceramic ring (21). Additionally, the height (27) of the titanium and the height (26) of the titanium alloy rings must be at least 30 μm. This is so that the gold alloy braze will not re-melt when the Ti and Ti-6Al-4V rings are laser welded.

[0011] Methods of assembly for the ceramic ring sandwich (20) include brazing together a sheet of ceramic material between a sheet of titanium and titanium alloy (Ti-6Al-4V) and then laser cutting a shape to fit the end of a given battery case. The sandwich can be cut into almost any desired geometrical shape. Another method is cutting out the ceramic ring (21) and the titanium alloy (Ti-6Al-4V) ring (22) and the titanium ring (23) separately and brazing the pieces together.

[0012] The titanium alloy (Ti-6Al-4V) case (2) has the desirable properties of titanium such as high strength for a relatively low weight; and the case has the requisite ability and electro-activity to be used a positive current carrying element where a battery's positive electrode exhibits more than 3.5 V vs. Li/Li⁺.

[0013] Typically, once the ceramic sandwich (20) is welded to the battery case (1), the battery electrodes (not shown) can be inserted into the case (2) and the feedthrough pin (not shown) inserted through the hole (5) in the lid (4). The feedthrough pin (not shown) is welded shut to provide a leak-tight seal. The battery (1) is filled with electrolyte (not shown) and laser welded closed on the bottom end (3). Tabs (not shown) which are connected to the positive electrode (not shown), can be folded out of the case (2) and laser welded at the same time as the bottom end cap (3).

[0014] While the invention herein disclosed has been described by means of specific embodiments and applications thereof, numerous modifications and variations could be made thereto by those skilled in the art without departing from the scope of the invention set forth in the claims. 

What is claimed is:
 1. A brazed ceramic ring sandwich for a lithium ion battery comprising a first ring of ceramic material; a second ring of titanium; a third ring of a titanium alloy of aluminum and vanadium, Ti-6Al-4V; a gold alloy braze with a gold content by weight of more than 50%; wherein said gold alloy braze attaches said second ring of titanium to said first ceramic material; wherein said gold alloy attaches said third ring of titanium alloy to the other edge of the ceramic ring.
 2. The brazed ceramic ring sandwich of claim 1 wherein the ceramic material is selected from the group consisting of aluminum oxide, zirconium oxide and zirconium oxide with 3% yttrium.
 3. The brazed ceramic ring sandwich of claim 1 wherein the gold alloy braze is 96.4% gold, 3.0% nickel and 0.6% titanium.
 4. The brazed ceramic ring sandwich of claim 1 wherein the ceramic ring is least 10 μm in height.
 5. The brazed ceramic ring sandwich of claim 1 wherein the height of the titanium ring must be at least 30 μm; and wherein the height of the titanium alloy, Ti-6Al-4V, ring must be at least 30 μm.
 6. A method for constructing the ceramic ring sandwich comprising the steps of brazing together a sheet of a ceramic material with a titanium sheet, on one side, and a titanium alloy, Ti-6Al-4V, sheet on the side; cutting the sandwich to a desired shape with a laser.
 7. The method of claim 6 comprising the step of selecting ceramic material from the group consisting of aluminum oxide, zirconium oxide and zirconium oxide with 3% yttrium.
 8. The method of claim 6 comprising the step of utilizing a gold alloy braze consisting mainly of 96.4% gold, 3.0% nickel and 0.6% titanium.
 9. The method of claim 6 comprising the step of selecting the height of the ceramic ring to be at least 10 μm.
 10. The method of claim 6 comprising the steps of selecting the height of the titanium ring to be at least 30 μm; and selecting the height of the titanium alloy, Ti-6Al-4V, ring to be at least 30 μm.
 11. A method for constructing a battery case comprising the steps of forming a cylinder of titanium alloy, Ti-6Al-4V; forming an end-cap of titanium alloy, Ti-6Al-4V, forming a ceramic ring sandwich of a ring of ceramic, a ring of titanium and a ring of a titanium alloy, Ti-6Al-4V, brazing said ceramic ring together with said titanium and titanium alloy rings wherein the ceramic ring is in the middle; forming a titanium end-cap with a feedthrough hole; welding the titanium alloy ring of the ceramic ring sandwich to the titanium alloy cylinder by laser welding; welding the titanium end-cap to the titanium ring of the ceramic ring sandwich by laser welding; and welding the titanium alloy end-cap to the titanium alloy cylinder.
 12. The method of claim 11 comprising the step of selecting ceramic material from the group consisting of aluminum oxide, zirconium oxide and zirconium oxide with 3% yttrium.
 13. The method of claim 11 comprising the step of utilizing a gold alloy braze consisting mainly of 96.4% gold, 3.0% nickel and 0.6% titanium.
 14. The method of claim 11 comprising the step of selecting the height of the ceramic ring to be at least 10 μm.
 15. The method of claim 11 comprising the steps of selecting the height of the titanium ring to be at least 30 μm; and selecting the height of the titanium alloy, Ti-6Al-4V, ring to be at least 30 μm. 